四氯合铝酸五铋

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| Formula = |Bi=5|Al=3|Cl=12
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| Appearance = 暗红色晶体
:4 Bi + BiCl3 + 3 AlCl3 → Bi5(AlCl4)3
它也可由相同的反应物在[BMIM]Cl/AlCl3（BMIM+=1-正丁基-3-甲基咪唑鎓）离子液体中于室温反应得到。

它也是氯化铝和硫化铋在[BMIM]Cl/AlCl3中反应的副产物。

参考文献