三氟甲磺酸亚铊是一种具有吸湿性的铊化合物,化学式为CF3SO3Tl。它可由碳酸亚铊和三氟甲磺酸反应制得。
它和二甲硫醚氯化亚金、六苯基-1,4,7,10-四磷杂癸烷(L)反应,可以得到Au4L24。它和Mo2Ni(dpa)4Cl2(dpa=二(2-吡啶基)胺)在乙腈中反应,可以得到Mo2Ni(dpa)4(CF3SO3)2。
参考文献
拓展阅读
- Petr Vaňura, David Sýkora, Tereza Uhlíková. Reaction of the thallium(I) cation with [2.2]paracyclophane: Experimental and theoretical study. Inorganica Chimica Acta, 2022. 543. 121205. .
- Seifert, Tim P.; Knoefel, Nicolai D. ; Feuerstein, Thomas J. ; Reiter, Kevin; Lebedkin, Sergei; Gamer, Michael T. ; Boukis, Andreas C.; Weigend, Florian; Kappes, Manfred M.; Roesky, Peter W. Size Matters: From Two-Dimensional Au(I)-Tl(I) Metallopolymers to Molecular Complexes by Simple Variation of the Steric Demand. Chemistry - A European Journal, 2019. 25 (15): 3799-3808. .
评论 (0)