天然镉({{chem2|_{48}Cd}})(原子量:112.411(8))有8种同位素。其中两种已经观测到天然放射性,另外三种预测可能发生衰变但尚未被观测到;可推测其半衰期极长。两种天然放射性同位素是 {{chem2|^{113}Cd}}(β衰变,半衰期)和{{chem2|^{116}Cd}}(雙β衰變,半衰期)。另外三种是{{chem2|^{106}Cd}},{{chem2|^{108}Cd}}(双电子俘获)和{{chem2|^{114}Cd}}(双β衰变);目前仅确定其衰变的下限值。只有三种同位素:{{chem2|^{110}Cd}},{{chem2|^{111}Cd}}和{{chem2|^{112}Cd}}在理论上是稳定的。在天然镉中不存在的同位素中,寿命最长的是半衰期为461.3天的{{chem2|^{109}Cd}}和半衰期为53.46小时的{{chem2|^{115}Cd}}。所有剩余的放射性同位素的半衰期都不到7小时,其中大多数都不到5分钟。该元素还存在12种已知亚稳态,其中最稳{{chem2|^{113m}Cd}}(半衰期13.9年)、{{chem2|^{115m}Cd}}(半衰期44.6天)和{{chem2|^{117m}Cd}}(半衰期3.44小时)。
已知的镉同位素范围从{{chem2|^{95}Cd}}到{{chem2|^{132}Cd}}。在稳定同位素{{chem2|^{112}Cd}} 之前,其主要衰变类型是电子捕获形成銀的同位素;之后则通过β衰变形成銦的同位素。
2021年的一项研究表明,在高离子强度条件下,镉同位素分馏主要取决于其与羧基位点的络合作用。而在低离子强度条件下,由静电吸引诱导的非特异性镉结合起主导作用,并在络合过程中促进镉同位素分馏。
圖表
|-
| 95Cd
| style="text-align:right" | 48
| style="text-align:right" | 47
| 94.94987(64)#
| 5# ms
|
|
| 9/2+#
|
|
|-
| 96Cd
| rowspan=2 style="text-align:right" | 48
| rowspan=2 style="text-align:right" | 49
| rowspan=2|96.93494(43)#
| rowspan=2|2.8(6) s
| (>99.9%)
| 97Ag
| rowspan=2|9/2+#
| rowspan=2|
| rowspan=2|
|-
| , (96Pd
|-
| rowspan=2|98Cd
| rowspan=2 style="text-align:right" | 48
| rowspan=2 style="text-align:right" | 50
| rowspan=2|97.92740(8)
| rowspan=2|9.2(3) s
| (99.975%)
| 98Ag
| rowspan=2|0+
| rowspan=2|
| rowspan=2|
|-
| , (.025%)
| 97Ag
|-
| style="text-indent:1em" | 98mCd
| colspan="3" style="text-indent:2em" | 2427.5(6) keV
| 190(20) ns
|
|
| 8+#
|
|
|-
| rowspan=3|99Cd
| rowspan=3 style="text-align:right" | 48
| rowspan=3 style="text-align:right" | 51
| rowspan=3|98.92501(22)#
| rowspan=3|16(3) s
| (99.78%)
| 99Ag
| rowspan=3|(5/2+)
| rowspan=3|
| rowspan=3|
|-
| , (.21%)
| 98Pd
|-
| , α (10−4%)
| 94Rh
|-
| 100Cd
| style="text-align:right" | 48
| style="text-align:right" | 52
| 99.92029(10)
| 49.1(5) s
|
| 100Ag
| 0+
|
|
|-
| 101Cd
| style="text-align:right" | 48
| style="text-align:right" | 53
| 100.91868(16)
| 1.36(5) min
|
| 101Ag
| (5/2+)
|
|
|-
| 102Cd
| style="text-align:right" | 48
| style="text-align:right" | 54
| 101.91446(3)
| 5.5(5) min
|
| 102Ag
| 0+
|
|
|-
| 103Cd
| style="text-align:right" | 48
| style="text-align:right" | 55
| 102.913419(17)
| 7.3(1) min
|
| 103Ag
| 5/2+
|
|
|-
| 104Cd
| style="text-align:right" | 48
| style="text-align:right" | 56
| 103.909849(10)
| 57.7(10) min
|
| 104Ag
| 0+
|
|
|-
| 105Cd
| style="text-align:right" | 48
| style="text-align:right" | 57
| 104.909468(12)
| 55.5(4) min
|
| 105Ag
| 5/2+
|
|
|-
| 106Cd
| style="text-align:right" | 48
| style="text-align:right" | 58
| 105.906459(6)
| colspan=3 align=center|觀測上穩定
| 0+
| 0.0125(6)
|
|-
| 107Cd
| style="text-align:right" | 48
| style="text-align:right" | 59
| 106.906618(6)
| 6.50(2) h
|
| 107mAg
| 5/2+
|
|
|-
| 108Cd
| style="text-align:right" | 48
| style="text-align:right" | 60
| 107.904184(6)
| colspan=3 align=center|觀測上穩定
| 0+
| 0.0089(3)
|
|-
| 109Cd
| style="text-align:right" | 48
| style="text-align:right" | 61
| 108.904982(4)
| 461.4(12) d
|
| 109Ag
| 5/2+
|
|
|-
| style="text-indent:1em" | 109m1Cd
| colspan="3" style="text-indent:2em" | 59.6(4) keV
| 12(2) µs
|
|
| 1/2+
|
|
|-
| style="text-indent:1em" | 109m2Cd
| colspan="3" style="text-indent:2em" | 463.0(5) keV
| 10.9(5) µs
|
|
| 11/2-
|
|
|-
| 110Cd
| style="text-align:right" | 48
| style="text-align:right" | 62
| 109.9030021(29)
| colspan=3 align=center|**'
| 0+
| 0.1249(18)
|
|-
| 111Cd
| style="text-align:right" | 48
| style="text-align:right" | 63
| 110.9041781(29)
| colspan=3 align=center|**'
| 1/2+
| 0.1280(12)
|
|-
| style="text-indent:1em" | 111mCd
| colspan="3" style="text-indent:2em" | 396.214(21) keV
| 48.50(9) min
| IT
| 111Cd
| 11/2-
|
|
|-
| 112Cd
| style="text-align:right" | 48
| style="text-align:right" | 65
| 112.9044017(29)
| 8.04(5)×1015 a
|
| 113In
| 1/2+
| 0.1222(12)
|
|-
| rowspan=2 style="text-indent:1em" | 113mCd
| 0+
| 0.2873(42)
|
|-
| 115Cd
| style="text-align:right" | 48
| style="text-align:right" | 67
| 114.9054310(29)
| 53.46(5) h
|
| 115mIn
| 1/2+
|
|
|-
| style="text-indent:1em" | 115mCd
| colspan="3" style="text-indent:2em" | 181.0(5) keV
| 44.56(24) d
|
| 115mIn
| (11/2)-
|
|
|-
| 116Cd
| style="text-align:right" | 48
| style="text-align:right" | 68
| 115.904756(3)
| 3.1(4)×1019 a
|
| 116Sn
| 0+
| 0.0749(18)
|
|-
| 117Cd
| style="text-align:right" | 48
| style="text-align:right" | 69
| 116.907219(4)
| 2.49(4) h
|
| 117mIn
| 1/2+
|
|
|-
| style="text-indent:1em" | 117mCd
| colspan="3" style="text-indent:2em" | 136.4(2) keV
| 3.36(5) h
|
| 117mIn
| (11/2)-
|
|
|-
| 118Cd
| style="text-align:right" | 48
| style="text-align:right" | 70
| 117.906915(22)
| 50.3(2) min
|
| 118In
| 0+
|
|
|-
| 119Cd
| style="text-align:right" | 48
| style="text-align:right" | 71
| 118.90992(9)
| 2.69(2) min
|
| 119mIn
| (3/2+)
|
|
|-
| style="text-indent:1em" | 119mCd
| colspan="3" style="text-indent:2em" | 146.54(11) keV
| 2.20(2) min
|
| 119mIn
| (11/2-)#
|
|
|-
| 120Cd
| style="text-align:right" | 48
| style="text-align:right" | 72
| 119.90985(2)
| 50.80(21) s
|
| 120In
| 0+
|
|
|-
| 121Cd
| style="text-align:right" | 48
| style="text-align:right" | 73
| 120.91298(9)
| 13.5(3) s
|
| 121mIn
| (3/2+)
|
|
|-
| style="text-indent:1em" | 121mCd
| colspan="3" style="text-indent:2em" | 214.86(15) keV
| 8.3(8) s
|
| 121mIn
| (11/2-)
|
|
|-
| 122Cd
| style="text-align:right" | 48
| style="text-align:right" | 74
| 121.91333(5)
| 5.24(3) s
|
| 122In
| 0+
|
|
|-
| 123Cd
| style="text-align:right" | 48
| style="text-align:right" | 75
| 122.91700(4)
| 2.10(2) s
|
| 123mIn
| (3/2)+
|
|
|-
| rowspan=2 style="text-indent:1em" | 123mCd
| rowspan=2 colspan="3" style="text-indent:2em" | 316.52(23) keV
| rowspan=2|1.82(3) s
|
| 123In
| rowspan=2|(11/2-)
| rowspan=2|
| rowspan=2|
|-
| IT
| 23Cd
|-
| 124Cd
| style="text-align:right" | 48
| style="text-align:right" | 76
| 123.91765(7)
| 1.25(2) s
|
| 124In
| 0+
|
|
|-
| 125Cd
| style="text-align:right" | 48
| style="text-align:right" | 77
| 124.92125(7)
| 0.65(2) s
|
| 125mIn
| (3/2+)#
|
|
|-
| style="text-indent:1em" | 125mCd
| colspan="3" style="text-indent:2em" | 50(70) keV
| 570(90) ms
|
| 125In
| 11/2-#
|
|
|-
| 126Cd
| style="text-align:right" | 48
| style="text-align:right" | 78
| 125.92235(6)
| 0.515(17) s
|
| 126In
| 0+
|
|
|-
| 127Cd
| style="text-align:right" | 48
| style="text-align:right" | 79
| 126.92644(8)
| 0.37(7) s
|
| 127mIn
| (3/2+)
|
|
|-
| 128Cd
| style="text-align:right" | 48
| style="text-align:right" | 80
| 127.92776(32)
| 0.28(4) s
|
| 128In
| 0+
|
|
|-
| rowspan=2|129Cd
| rowspan=2 style="text-align:right" | 48
| rowspan=2 style="text-align:right" | 81
| rowspan=2|128.93215(32)#
| rowspan=2|242(8) ms
| (>99.9%)
| 129In
| rowspan=2|3/2+#
| rowspan=2|
| rowspan=2|
|-
| IT (129Cd
|-
| style="text-indent:1em" | 129mCd
| colspan="3" style="text-indent:2em" | 0(200)# keV
| 104(6) ms
|
|
| 11/2-#
|
|
|-
| rowspan=2|130Cd
| rowspan=2 style="text-align:right" | 48
| rowspan=2 style="text-align:right" | 82
| rowspan=2|129.9339(3)
| rowspan=2|162(7) ms
| (96%)
| 130In
| rowspan=2|0+
| rowspan=2|
| rowspan=2|
|-
| , (4%)
| 129In
|-
| 131Cd
| style="text-align:right" | 48
| style="text-align:right" | 83
| 130.94067(32)#
| 68(3) ms
|
|
| 7/2-#
|
|
|-
| 132Cd
| style="text-align:right" | 48
| style="text-align:right" | 84
| 131.94555(54)#
| 97(10) ms
|
|
| 0+
|
|
|}
镉-113m
镉-113m(也写作“113mCd”)镉元素的一种放射性同位素及同质异能素,具有约14.1年的半衰期。在普通热核反应堆中,它的裂变产物产额很低;而且它具有极强的中子俘获能力,使得核反应中产生的少量的镉-113m也会被核燃料的“燃烧”耗尽,因此这种同位素只占核废料的极小部分。
快速裂变或一些相对原子质量较大的锕系元素的裂变中会产生较高产量的113mCd。
另见
- 錫的同位素
- 銦的同位素
- 銀的同位素
- 鈀的同位素
- 銠的同位素
注释
参考文獻
- Isotope masses from [https://web.archive.org/web/20080923134436/http://www.nndc.bnl.gov/amdc/index.html Ame2003 Atomic Mass Evaluation] by G. Audi, A.H. Wapstra, C. Thibault, J. Blachot and O. Bersillon in Nuclear Physics A729 (2003).
- Isotopic compositions and standard atomic masses from [http://www.iupac.org/publications/pac/2003/7506/7506x0683.html Atomic weights of the elements. Review 2000 (IUPAC Technical Report)] . Pure Appl. Chem. Vol. 75, No. 6, pp. 683-800, (2003) and [http://www.iupac.org/news/archives/2005/atomic-weights_revised05.html Atomic Weights Revised (2005)] .
- Half-life, spin, and isomer data selected from these sources. Editing notes on this article's talk page.
** Audi, Bersillon, Blachot, Wapstra. [http://amdc.in2p3.fr/web/nubase_en.html The Nubase2003 evaluation of nuclear and decay properties] , Nuc. Phys. A 729, pp. 3-128 (2003).
** National Nuclear Data Center, Brookhaven National Laboratory. Information extracted from the [http://www.nndc.bnl.gov/nudat2/ NuDat 2.1 database] (retrieved Sept. 2005).
* David R. Lide (ed.), Norman E. Holden in CRC Handbook of Chemistry and Physics, 85th Edition*, online version. CRC Press. Boca Raton, Florida (2005). Section 11, Table of the Isotopes.
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