{{Chembox
| verifiedrevid = 428834649
| ImageFile =Beryllium azide.svg
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| IUPACName = Beryllium azide
| OtherNames =
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|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
| REL = Ca C 0.0005 mg/m3 (as Be)
| IDLH = Ca [4 mg/m3 (as Be)]
:BeCl2 + 2Me3SiN3 → Be(N3)2 + 2Me3SiCl
此外,二甲基铍在干乙醚中和叠氮酸于−116 °C反应也能得到叠氮化铍:
:Be(CH3)2 + 2HN3 → Be(N3)2 + 2CH4
结构
根据红外光谱及拉曼光谱,叠氮化铍的结构是无限链状结构,四面体配位的Be2+离子由末端桥联的N3−连接。
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