{{chembox
| Verifiedfields = changed
| verifiedrevid = 403120211
| Name = 硫酸铀(IV)
| CustomizedImage=\mathrm{ \ \Biggl[}\mathrm{ \ \!\ \Biggr]_2}
| OtherNames = 硫酸铀、二硫酸铀
| NameEn = Uranium(IV) sulfate
| Section1 =
| Section2 = {{Chembox Properties
| Formula = U(SO4)2
| MolarMass =430.15(无水)502.22(四水)
| Density = 3.6 g·cm-3(四水)
: UO2SO4 + 2H2SO4 → U(SO4)2 + 4H2O
相关物种
UIV-SO4可以形成离子及配合物,如USO42+、[U(SO4)5(H2O)]6−等。
参考文献
拓展阅读
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- Merkel, B.; Hasche-Berger, A. (2008). Uranium, Mining and Hydrogeology. Springer.
- Hennig, C.; Schmeide, K.; Brendler, V.; Moll, H.; Tsushima, S.; Scheinost, A.C. (2007). “EXAFS Investigation of U(VI), U(IV), and Th(IV) Sulfato Complexes in Aqueous Solution”. Inorganic Chemistry 46 (15): 5882–5892.
- Cardenas, E.; Watson, D.; Gu, B.; Ginder-Vogel, M.; Kitanidis, P.K.; Jardin, P.M.; Wu, W.; Leigh, M.B.; Carley, J.; Carroll, S.; Gentry, T.; Luoe, J.; Zhou, J.; Criddle, C.S.; Marsh, T.L.; Tiedje, J.M. (2010). “Significant Association between Sulfate-Reducing Bacteria and Uranium-Reducing Microbial Communities as Revealed by a Combined Massively Parallel Sequencing-Indicator Species Approach”. Applied and Environmental Microbiology 76 (20): 6778-6786.
- Converse, B.J.; Wua, T.; Findlay, R.H.; Roden, E.E. (2013). “U(VI) Reduction in Sulfate-Reducing Subsurface Sediments Amended with Ethanol or Acetate”. Applied and Environmental Microbiology 79 (13): 4173-4177.
- Day, R. A.; Wilhite, R. N.; Hamilton, F.R. (1955). “Stability of Complexes of Uranium(IV) with Chloride, Sulfate and Thiocyanate”. Journal of the American Chemical Society 77 (12):3180-3182.
- Hennig, C.; Kraus, W.; Emmerling, F.; Ikeda, A.;. Scheinost, A.C. (2008). “Coordination of a Uranium(IV) Sulfate Monomer in an Aqueous Solution and in the Solid State”. Inorganic Chemistry 47 (5): 1634-1638.
- Plášil, J.; Fejfarová, K.; Novák, M.; Dušek, M.; Škoda, R.; Hloušek, J.; Čejka, J.; Majzlan, J.; Sejkora, J.; Machovič, V.; Talla, D. (2011). “Běhounekite, U(SO4)2(H2O)4, from Jáchymov (St Joachimsthal), Czech Republic: the first natural U4+ sulphate”. Mineralogical Magazine 75 (6): 2739-2753.
- Mudd, G.M. (2001). “Critical Review of Acid in situ leach uranium mining: 1. USA and Australia”. Environmental Geology 41 (3-4): 390-403.
- Závodská, L.; Kosorínová, E.; Scerbáková, L.; Lesny, J. (2008). “Environmental Chemistry of Uranium”. HV .
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