二硒化氫

二硒化氫(),又稱乙硒烷二硒烷,是一種無機硒化合物,其化學式為H2Se2,亦可計為(SeH)2,其結構類似於過氧化氫(H2O2)、硫氧化氫(H2SO)與二硫化氫(H2S2),但比前三者更接近90度。用铝还原二氧化硒的盐酸溶液,放出的气体与乙酸铅反应生成的黑色沉淀中含有PbSe₂,证明二硒化氢存在于气体混合物当中。。二硒化氫常溫下容易分解為硒化氫(H2Se)和硒單質而無法穩定存在,但可以在一些溶液中存在。

結構
二硒化氫分子的兩面角為89.9度,H-Se-Se鍵角為90.5度,H-Se鍵長為1.536埃,Se-Se鍵長為2.380埃。二硒化氫扭轉運動電勢能壘高度與硫氧化氫類似,而扭轉穿隧的分解則與二硫化氫有相同的觀測值。此外,二硒化氫和二碲化氫(hydrogen ditelluride)的分子結構都有轉動屏障的現象。

結構類似的化合物
還有一些硒化合物的結構類似過氧化氫,如硒氧化氫、硒硫化氫,但他們都不穩定。

參考文獻
#Héctor García-Marín, John C. van der Toorn, José A. Mayoral, José I. García and Isabel W. C. E. Arends. Glycerol-based solvents as green reaction media in epoxidations with hydrogen peroxide catalysed by bis[3,5-bis(trifluoromethyl)-diphenyl] diselenide, Green Chem., 2009, 11, 1605.
#Charlotte Gabel-Jensen, Kristoffer Lunøe and Bente Gammelgaard. Formation of methylselenol, dimethylselenide and dimethyldiselenide in in vitro metabolism models determined by headspace GC-MS, Metallomics, 2010, 2, 167.
#Wei-Wei Xiong, Jian-Rong Li, Mei-Ling Feng and Xiao-Ying Huang. Solvothermal syntheses, crystal structures, and characterizations of a series of one-dimensional organic-containing gallium polyselenides, CrystEngComm, 2011, 13, 6206.
#Xin Huang, Xiaoman Liu, Quan Luo, Junqiu Liu and Jiacong Shen. Artificial selenoenzymes: Designed and redesigned, Chem. Soc. Rev., 2011, 40, 1171.

评论 (0)

  • 还没有评论,来抢沙发吧。